Perovskite solar cell based on hole-selective interlayer achieves 26.39% efficiency
Scientists from Huaqiao University in China have designed a perovskite solar cell that utilizes a hole-selective interlayer inhibiting ion diffusion to increase the device's stability.
Ion migration is considered the key cause of instability for perovskite solar cells. It occurs when the soft crystal lattice and relatively weak bonds in the perovskite film lead to low formation energies of defects, so heat and light could easily activate ionic defects within the perovskite lattice. The accumulation of ions deforms the local crystal structure and degrades the perovskite film, both the electron transport layer (ETL) and hole transport layer (HTL), as well as the electrodes.
“The idea of incorporating a hole-selective interlayer in perovskite solar cells was inspired by proton exchange membrane (PEM) fuel cells, where the PEM serves as a proton conductor while blocking the diffusion of other chemical species,” the researchers explained. “Designing internal barriers that block the layer-to-layer ion diffusion is critically important to improve the operation lifetime of perovskite solar cells.”
The research team built the hole-selective interlayer with an ultrathin polymeric material known as PDTBT2T-FTBDT (D18), which reportedly offers conformal coverage on the surface of perovskite film due to the high fluidity of its diluted solution. It also features matched energy level alignment with the perovskite absorber and the Spiro-OMeTAD HTL.
The academics deposited the interlayer by spin-coating a hot chlorobenzene (CB) solution of D18 on top of the perovskite film, which reportedly led to the formation of a dense membrane. They constructed the solar cell with a substrate made of glass and fluorine-doped tin oxide (FTO), an ETL based on tin oxide (SnO2), a perovskite absorber, the D18 interlayer, the Spiro-OMeTAD HTL, and a gold (Au) metal contact.
The group assessed the interlayer's effectiveness of inhabiting ion diffusion and found it provides superior performance compared to the most commonly used polymers P3HT and PTAA. “The results show that the D18 layer has robust ion-blocking capability under thermal stress,” it further explained. “D18 is in close contact with the perovskite grain and grain boundary, providing conformal coverage.”
The proposed 0.12 cm2 solar cell was tested under standard illumination conditions and was found to achieve a power conversion efficiency of 26.39%, an open-circuit voltage of 1.185 V, a short-circuit current of 26.54 mA cm−2, and a fill factor of 83.92%. For comparison, a reference cell built without the D18 layer reached an efficiency of 24.43%, an open-circuit voltage of 1.152 V, a short-circuit current of 26.39 mA cm−2, and a fill factor of 80.37%.
“We have shown that the introduction of the polymeric D18 interlayer can effectively block layer-to-layer ion diffusion within perovskite solar cells while maintaining highly efficient hole transport, leading to significantly improved stability of the n-i-p cells with a certified efficiency of over 26%,” the researchers said, noting that the cell was also able to retain 95.4% of its initial efficiency after 1,100 h.
They also claimed the device is currently the “most stable” perovskite solar cell with high efficiency levels.
The new cell concept was presented in the study “Ultrathin polymer membrane for improved hole extraction and ion blocking in perovskite solar cells,” which was recently published in nature communications.
Customized/OEM/ODM Service
HomSolar Supports Lifepo4 battery pack customization/OEM/ODM service, welcome to contact us and tell us your needs.
HomSolar: Your One-stop LiFePO4 Battery Pack & ESS Solution Manufacturer
Our line of LiFePO4 (LFP) batteries offer a solution to demanding applications that require a lighter weight, longer life, and higher capacity battery. Features include advanced battery management systems (BMS), Bluetooth® communication and active intelligent monitoring.
Customised Lithium Iron Phosphate Battery Casing
ABS plastic housing, aluminium housing, stainless steel housing and iron housing are available, and can also be designed and customised according to your needs.
HomSolar Smart BMS
Intelligent Battery Management System for HomSolar Energy Storage System. Bluetooth, temperature sensor, LCD display, CAN interface, UART interface also available.
Terminals & Plugs Can Be Customized
A wide range of terminals and plugs can be customised to suit the application needs of your battery products.
Well-designed Solutions for Energy Storage Systems
We will design the perfect energy storage system solution according to your needs, so that you can easily solve the specific industry applications of battery products.
About Our Battery Cells
Our energy storage system products use brand new grade A LiFePO4 cells with a battery lifespan of more than 4,000 charge/discharge cycles.
Applications in Different Industries
We supply customized & OEM battery pack, assemble cells with wiring, fuse and plastic cover, all the cell wires connected to PCB plug or built BMS.
Applications: E-bike, Electric Scooter, Golf Carts, RV, Electric Wheelchair, Electric Tools, Robot Cleaner, Robot Sweeper, Solar Energy Storage System, Emergency Light, Solar Power Light, Medical Equipment, UPS Backup Power Supply.
We can provide you with customized services. We have the ability to provide a vertical supply chain, from single cells to pack/module and to a complete power solution with BMS, etc.
HomSolar (Shenzhen) Technology Co., Ltd
