Perovskite-silicon tandem solar cell based on indium oxide buffer layer achieves 30.04% efficiency
Researchers at the Northwestern Polytechnical University in China have fabricated a four-terminal (4T) semi-transparent perovskite-silicon tandem solar cell based on a top perovskite cell integrating an indium oxide (In2O3) sputtering buffer layer (SBL) deposited through a low-cost approach for industrial applications.
SBLs are used in perovskite-silicon tandem devices to prevent bombardment damage during the indium tin oxide (ITO) transparent electrode deposition, protecting the underlying perovskite absorber and the electron transport layer (ETL).
“The In2O3 SBL was fabricated using the e-beam evaporation technique, a solvent-free process compatible with industrial production,” the research's lead author, Li Can, told pv magazine. “The optical and electrical properties of the In2O3 film exhibited a strong dependence on the deposition rate. Higher deposition rate resulted in In-rich In2O3 films with poor transmittance and increased parasitic absorption. Through optimization of the deposition rate, we achieved stoichiometric In2O3 films, featuring high transmittance and robust protective properties.”
The research team built the top perovskite device with a substrate made of glass and ITO, a self-assembled monolayer (SAM) made of nickel(II) oxide (NiO), the perovskite absorber, an ETL relying on buckminsterfullerene (C60), a bathocuproine (BCP) buffer layer, the In2O3 SBL, and the ITO electrode.
This cell achieved a power conversion efficiency of 20.20%, which the scientists said is close to that of its opaque counterpart, while also showing excellent electrical, optical, and protective properties of the In2O3 layer, with the energy bandgap being 1.68 eV.
“In2O3 films with a thickness of 20 nm effectively protected the underlying perovskite film and ETL from bombardment damage during ITO sputtering,” Can explained. “Various characterizations, including cross-sectional SEM, X-ray diffraction, and steady-state photoluminescence, confirmed this superior protection effect.”
The academics then integrated the top perovskite cell with a silicon bottom cell in a tandem device that achieved an efficiency of 30.04%. This cell was also able to retain around 80% of its initial efficiency after 423 h of continuous light. They claim the cell is one of the highest-performing 4T perovskite-Si tandem solar cells to date.
The description of the device is available in the study “Indium oxide buffer layer for perovskite/Si 4-terminal tandem solar cells with efficiency exceeding 30%,” published in the Journal of Energy Chemistry.
“Our work expands the limited selection of available SBL materials for p-i-n structured ST-PSCs and introduced a low-cost deposition approach for industrial applications,” Can concluded. “This work demonstrates significant potential for accelerating commercialization and widespread application of perovskite photovoltaics.”
Customized/OEM/ODM Service
HomSolar Supports Lifepo4 battery pack customization/OEM/ODM service, welcome to contact us and tell us your needs.
HomSolar: Your One-stop LiFePO4 Battery Pack & ESS Solution Manufacturer
Our line of LiFePO4 (LFP) batteries offer a solution to demanding applications that require a lighter weight, longer life, and higher capacity battery. Features include advanced battery management systems (BMS), Bluetooth® communication and active intelligent monitoring.
Customised Lithium Iron Phosphate Battery Casing
ABS plastic housing, aluminium housing, stainless steel housing and iron housing are available, and can also be designed and customised according to your needs.
HomSolar Smart BMS
Intelligent Battery Management System for HomSolar Energy Storage System. Bluetooth, temperature sensor, LCD display, CAN interface, UART interface also available.
Terminals & Plugs Can Be Customized
A wide range of terminals and plugs can be customised to suit the application needs of your battery products.
Well-designed Solutions for Energy Storage Systems
We will design the perfect energy storage system solution according to your needs, so that you can easily solve the specific industry applications of battery products.
About Our Battery Cells
Our energy storage system products use brand new grade A LiFePO4 cells with a battery lifespan of more than 4,000 charge/discharge cycles.
Applications in Different Industries
We supply customized & OEM battery pack, assemble cells with wiring, fuse and plastic cover, all the cell wires connected to PCB plug or built BMS.
Applications: E-bike, Electric Scooter, Golf Carts, RV, Electric Wheelchair, Electric Tools, Robot Cleaner, Robot Sweeper, Solar Energy Storage System, Emergency Light, Solar Power Light, Medical Equipment, UPS Backup Power Supply.
We can provide you with customized services. We have the ability to provide a vertical supply chain, from single cells to pack/module and to a complete power solution with BMS, etc.
HomSolar (Shenzhen) Technology Co., Ltd
